Z = number of protons
In a neutral atom, the number of protons in a nucleus is exactly equal to the number of electrons outside the nucleus. Consider, for example, the elements hydrogen (Z = 1) and uranium (Z = 92). All hydrogen atoms have one proton in the nucleus, all uranium atoms have 92. In a neutral hydrogen atom there is one electron outside the nucleus; in a uranium atom there are 92.
H atom: 1 proton, 1 electron Z=1
U atom: 92 protons, 92 electrons Z=92
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